The incorporation of thioether groups in the structure of a Mn-12 single-molecule magnet, [Mn12O12(L)(16)(H2O)(4)] with L = 4-(methylthio) benzoate, is a successful route to the deposition of well-separated clusters on native gold surfaces and to the addressing of individual molecules by scanning tunnelling microscopy.
Isolated single-molecule magnets on native gold / ZOBBI L.; MANNINI M.; PACCHIONI M.; CHASTANET G.; BONACCHI D.; ZANARDI C.; BIAGI R.; DEL PENNINO U.; GATTESCHI D.; CORNIA A.; SESSOLI R.. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 12:(2005), pp. 1640-1642. [10.1039/b418072k]
Isolated single-molecule magnets on native gold
MANNINI, MATTEO;PACCHIONI, MIRKO;BONACCHI, DANIELE;BIAGI, ROBERTO;GATTESCHI, DANTE;SESSOLI, ROBERTA
2005
Abstract
The incorporation of thioether groups in the structure of a Mn-12 single-molecule magnet, [Mn12O12(L)(16)(H2O)(4)] with L = 4-(methylthio) benzoate, is a successful route to the deposition of well-separated clusters on native gold surfaces and to the addressing of individual molecules by scanning tunnelling microscopy.
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