The straightforward synthesis of new enantiopure y-aminoalcohols through 1,3-dipolar cycloadditon to a chiral cyclic nitrone derived from L-malic acid is described. Results of the application of these compounds as chiral catalysts in the alkylation of benzaldehyde with diethylzinc are also reported.
Synthesis of New Enantiopure γ-Aminoalcohols: Their Use as Catalysts in the Alkylation of Benzaldehyde by Diethylzinc / S. Cicchi; S. Crea; A. Goti; A. Brandi. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - STAMPA. - 8:(1997), pp. 293-301. [10.1016/S0957-4166(96)00502-2]
Synthesis of New Enantiopure γ-Aminoalcohols: Their Use as Catalysts in the Alkylation of Benzaldehyde by Diethylzinc
CICCHI, STEFANO;GOTI, ANDREA;BRANDI, ALBERTO
1997
Abstract
The straightforward synthesis of new enantiopure y-aminoalcohols through 1,3-dipolar cycloadditon to a chiral cyclic nitrone derived from L-malic acid is described. Results of the application of these compounds as chiral catalysts in the alkylation of benzaldehyde with diethylzinc are also reported.
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