The solvothermal synthesis, crystal structure and preliminary magnetic studies are reported of the first high nuclearity VIII-based polyoxo(alkoxo)vanadium cage, a VIII16VIV2 complex.
A high-nuclearity, beyond ‘‘fully reduced’’ polyoxo(alkoxo) vanadium(III/IV) cage / I. S. TIDMARSH; R. H. LAYE; P. R. BREARLEY; M. SHANMUGAM; E. C. SANUDO; L. SORACE; A. CANESCHI; E. J. L. MCINNES. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 24:(2006), pp. 2560-2562. [10.1039/b605106e]
A high-nuclearity, beyond ‘‘fully reduced’’ polyoxo(alkoxo) vanadium(III/IV) cage
SORACE, LORENZO;CANESCHI, ANDREA;
2006
Abstract
The solvothermal synthesis, crystal structure and preliminary magnetic studies are reported of the first high nuclearity VIII-based polyoxo(alkoxo)vanadium cage, a VIII16VIV2 complex.
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