The P4 molecule bound to ruthenium as an g 1 -ligand in [CpRu(PPh 3 ) 2 (g 1 -P 4 )]Y (Y = PF 6 , CF 3 SO 3 ) undergoes an easy reaction with water in exceedingly mild conditions to yield PH3 , which remains coordinated to the [CpRu(PPh 3 ) 2 ]fragment, and oxygenated derivatives.
Easy hydrolysis of white phosphorus coordinated to ruthenium / M. DI VAIRA; P. FREDIANI; S. SENIORI COSTANTINI; M. PERUZZINI; P. STOPPIONI. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - STAMPA. - nessuno:(2005), pp. 2234-2236. [10.1039/B504795A]
Easy hydrolysis of white phosphorus coordinated to ruthenium
DI VAIRA, MASSIMO;FREDIANI, PIERO;SENIORI COSTANTINI, STEFANO;PERUZZINI, MAURIZIO;STOPPIONI, PIERO
2005
Abstract
The P4 molecule bound to ruthenium as an g 1 -ligand in [CpRu(PPh 3 ) 2 (g 1 -P 4 )]Y (Y = PF 6 , CF 3 SO 3 ) undergoes an easy reaction with water in exceedingly mild conditions to yield PH3 , which remains coordinated to the [CpRu(PPh 3 ) 2 ]fragment, and oxygenated derivatives.
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