Successfully tamed: When coordinated to two {CpRu(PPh3)2} moieties, white phosphorus (P4) reacts selectively with a large excess of water to yield phosphorous acid (H3PO3) and the previously unknown 1-hydroxytriphosphane (PH(OH)PHPH2), which is stabilized as a bridging ligand by coordination to the ruthenium moieties
Controlling the activation of white phosphorus: formation of phosphorous acid and ruthenium-coordinated 1-hydroxytriphosphane by hydrolysis of double metallated P4 / P. BARBARO; M. DI VAIRA; M. PERUZZINI; S. SENIORI COSTANTINI; P. STOPPIONI. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 47:(2008), pp. 4225-4227.
Controlling the activation of white phosphorus: formation of phosphorous acid and ruthenium-coordinated 1-hydroxytriphosphane by hydrolysis of double metallated P4
DI VAIRA, MASSIMO;PERUZZINI, MAURIZIO;SENIORI COSTANTINI, STEFANO;STOPPIONI, PIERO
2008
Abstract
Successfully tamed: When coordinated to two {CpRu(PPh3)2} moieties, white phosphorus (P4) reacts selectively with a large excess of water to yield phosphorous acid (H3PO3) and the previously unknown 1-hydroxytriphosphane (PH(OH)PHPH2), which is stabilized as a bridging ligand by coordination to the ruthenium moieties
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