During the last 50 years, formation of the highly chromogenic copper cuprizone complex has been exploited for spectrophotometric determinations of copper although the precise chemical nature of the resulting species has never been ascertained; we eventually show here, in contrast to current opinion, that copper cuprizone is a copper(III) complex.
Unravelling the Chemical Nature of Copper Cuprizone / L. MESSORI; A. CASINI; C. GABBIANI; L. SORACE; M. MUNIZ-MIRANDA; P. ZATTA. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - STAMPA. - 1:(2007), pp. 2112-2114. [10.1039/b701896g]
Unravelling the Chemical Nature of Copper Cuprizone
MESSORI, LUIGI;GABBIANI, CHIARA;SORACE, LORENZO;MUNIZ-MIRANDA, MAURIZIO;
2007
Abstract
During the last 50 years, formation of the highly chromogenic copper cuprizone complex has been exploited for spectrophotometric determinations of copper although the precise chemical nature of the resulting species has never been ascertained; we eventually show here, in contrast to current opinion, that copper cuprizone is a copper(III) complex.
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