We have recorded the molecular beam, fluorescence excitation spectra for the 0(0)(0), 6a(0)(1), I-0(2), and 1(0)(1), rovibronic bands of the S-1 (B-1(2)) <-- S-0 ((1)A(1)) electronic transition in aniline at a resolution of 0.0005 cm(-1). The observed transitions were fit to a rigid-rotor Hamiltonian, and accurate rotational constants were obtained for each band.
Molecular beam spectroscopy of S1 aniline: assignments for the 000, 6a01,I02 and 101 rovibronic bands / E. R. TH. KERSTEL; M. BECUCCI; G. PIETRAPERZIA; D. CONSALVO; E. CASTELLUCCI. - In: JOURNAL OF MOLECULAR SPECTROSCOPY. - ISSN 0022-2852. - STAMPA. - 177:(1996), pp. 74-78. [10.1006/jmsp.1996.0119]
Molecular beam spectroscopy of S1 aniline: assignments for the 000, 6a01,I02 and 101 rovibronic bands
BECUCCI, MAURIZIO;PIETRAPERZIA, GIANGAETANO;CASTELLUCCI, EMILIO MARIO
1996
Abstract
We have recorded the molecular beam, fluorescence excitation spectra for the 0(0)(0), 6a(0)(1), I-0(2), and 1(0)(1), rovibronic bands of the S-1 (B-1(2)) <-- S-0 ((1)A(1)) electronic transition in aniline at a resolution of 0.0005 cm(-1). The observed transitions were fit to a rigid-rotor Hamiltonian, and accurate rotational constants were obtained for each band.
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