Ringing the changes: Complexes of azamacrocycles were used for the template synthesis of extraordinary new cyclic and acyclic chromium–nickel chains, which include the “S”-shaped cluster shown (see picture) obtained when a cyclen-based template is used. The results suggest a new method for making sophisticated polymetallic architectures.
Templating Open- and Closed-Chain Structures Around Metal Complexes of Macrocycles / S. L. HEATH; R. H. LAYE; C. A. MURYN; N. LIMA; R. SESSOLI; R. SHAW; S. J. TEAT; G. A. TIMCO; R. E. R. WINPENNY. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 43:(2004), pp. 6132-6135. [10.1002/anie.200461006]
Templating Open- and Closed-Chain Structures Around Metal Complexes of Macrocycles
SESSOLI, ROBERTA;
2004
Abstract
Ringing the changes: Complexes of azamacrocycles were used for the template synthesis of extraordinary new cyclic and acyclic chromium–nickel chains, which include the “S”-shaped cluster shown (see picture) obtained when a cyclen-based template is used. The results suggest a new method for making sophisticated polymetallic architectures.
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