The Zn-II and Cu-II complexes with the macrocyclic ligand [15]aneN(3)O(2) (L) readily trap atmospheric CO2 to form the {[ZnL](3)(mu(3)-CO3)}.(ClO4)(4) and {[CuL](3)(mu(3)-CO3)}.(ClO4)(4) complexes, which both contain a triply bridging carbonate anion.
Copper(II) and zinc(II) macrocyclic complexes with high efficiency in fixing CO2. Crystall structures of [[ZnL]3(mu3-CO3)].(ClO4)4 and [[CuL]3(mu3-CO3)].(ClO4)4 (L = [15]ane N3O2) / C. BAZZICALUPI; A. BENCINI; A. BIANCHI; V. FUSI; P. PAOLETTI; B. VALTANCOLI. - In: CHEMICAL COMMUNICATIONS. - ISSN 0366-5607. - STAMPA. - .....:(1995), pp. 1555-1556.
Copper(II) and zinc(II) macrocyclic complexes with high efficiency in fixing CO2. Crystall structures of [[ZnL]3(mu3-CO3)].(ClO4)4 and [[CuL]3(mu3-CO3)].(ClO4)4 (L = [15]ane N3O2)
BAZZICALUPI, CARLA;BENCINI, ANDREA;BIANCHI, ANTONIO;VALTANCOLI, BARBARA
1995
Abstract
The Zn-II and Cu-II complexes with the macrocyclic ligand [15]aneN(3)O(2) (L) readily trap atmospheric CO2 to form the {[ZnL](3)(mu(3)-CO3)}.(ClO4)(4) and {[CuL](3)(mu(3)-CO3)}.(ClO4)(4) complexes, which both contain a triply bridging carbonate anion.
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