Abstract—Protodesilylaton of substituted silyl dithianes occurs with clean retention of configuration. In the case of the 2-phenyl derivative, epimerization of C-2 occurs. Selective functionalization of 2,2-bis trimethylsilyl derivatives can be efficiently obtained.
STEREOCONSERVATIVE PROTODESILYLATION OF SUBSTITUTED SILYL DITHIANES / V. CERÈ; A. CAPPERUCCI; A. DEGL'INNOCENTI; S. POLLICINO. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 47:(2006), pp. 7525-7528.
STEREOCONSERVATIVE PROTODESILYLATION OF SUBSTITUTED SILYL DITHIANES
CAPPERUCCI, ANTONELLA;DEGL'INNOCENTI, ALESSANDRO;
2006
Abstract
Abstract—Protodesilylaton of substituted silyl dithianes occurs with clean retention of configuration. In the case of the 2-phenyl derivative, epimerization of C-2 occurs. Selective functionalization of 2,2-bis trimethylsilyl derivatives can be efficiently obtained.
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