Summary:Regioselective opening of the thiirane ring occurs spontaneously with Group IV B organometallics such as Me3SnNR2 and under the catalytic action of AICl3 with Me3SiCN,affording difunctional thiols.
Ring opening reactions of thiiranes with group IVB organometallics: a new regioselective route to beta-amino and beta-cyanide thiols / M. TADDEI; A.M. PAPINI; M. FIORENZA; A. RICCI; G. SECONI. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 24:(1983), pp. 2311-2314.
Ring opening reactions of thiiranes with group IVB organometallics: a new regioselective route to beta-amino and beta-cyanide thiols.
PAPINI, ANNA MARIA;
1983
Abstract
Summary:Regioselective opening of the thiirane ring occurs spontaneously with Group IV B organometallics such as Me3SnNR2 and under the catalytic action of AICl3 with Me3SiCN,affording difunctional thiols.
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