Different silylated 1,2-dithiins, obtained through self-dimerization of the related a,b-ethylenic thioacylsilanes, in the presence of AlCl3 show an unusual rearrangement leading in good yields to novel silyl-endodisulfide bicyclic systems.
UNUSUAL CHEMICAL BEHAVIOUR OF SILYLATED 1,2-DITHIINS UNDER LEWIS ACID CONDITIONS / A. DEGL'INNOCENTI; A. CAPPERUCCI ; MALESCI I.; CASTAGNOLI G.. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - ELETTRONICO. - 46:(2005), pp. 4711-4713. [10.1016/j.tetlet.2005.05.048]
UNUSUAL CHEMICAL BEHAVIOUR OF SILYLATED 1,2-DITHIINS UNDER LEWIS ACID CONDITIONS
DEGL'INNOCENTI, ALESSANDRO;CAPPERUCCI, ANTONELLA;
2005
Abstract
Different silylated 1,2-dithiins, obtained through self-dimerization of the related a,b-ethylenic thioacylsilanes, in the presence of AlCl3 show an unusual rearrangement leading in good yields to novel silyl-endodisulfide bicyclic systems.
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