A decacopper(II) cluster. Clusters (shown in blue) can be expanded and their magnetic properties tuned by the addition of suitable metal-complex ligands (shown in green). By using this method, [Cu6{(PhSiO2)6}2{(NC)Cu(tmpa)}4](PF6)4 was rationally designed by self-assembly of four {(NC)Cu(tmpa)}+ units around a robust hexacopper(II)-siloxanolate cage (tmpa=tris(2-pyridylmethyl)amine).
Toward Stepwise Cluster Assemby: a Decanuclear Copper(II) complex obtained by Controlled Expansion of Metallosiloxane Cage / G.L. ABBATI; A. CANESCHI; A. CORNIA; A.C. FABRETTI; Y.A. POZDNIAKOVA; O.I. SCHEGOLIKHINA. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 41:(2002), pp. 4517-4520. [10.1002/1521-3773(20021202)41:23<4517::AID-ANIE4517>3.0.CO;2-G]
Toward Stepwise Cluster Assemby: a Decanuclear Copper(II) complex obtained by Controlled Expansion of Metallosiloxane Cage
CANESCHI, ANDREA;
2002
Abstract
A decacopper(II) cluster. Clusters (shown in blue) can be expanded and their magnetic properties tuned by the addition of suitable metal-complex ligands (shown in green). By using this method, [Cu6{(PhSiO2)6}2{(NC)Cu(tmpa)}4](PF6)4 was rationally designed by self-assembly of four {(NC)Cu(tmpa)}+ units around a robust hexacopper(II)-siloxanolate cage (tmpa=tris(2-pyridylmethyl)amine).
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