A new approach to the synthesis of chiral P,N-ligands containing a stereogenic phosphorus atom is reported; the synthesis, characterization and coordination properties of (PR, 2R, 3R, 2'R, 3'S, 4'S) 2[2'(3',4'-di-tert-butoxy-1'-methyltetrahydropyrrolyl)]-3-methoxy-1-phenyltetrahydrophosphole (P*-N-1), which contains a stereogenic phosphorus in addition to five contiguous stereocentres in the ligand backbone; compound P*-N-1 represents the first example of a new class of chiral P,N-ligands with the heteroatoms incorporated in two 2,2'-coupled pyrrolidine-phospholane rings.

A New P-Chiral Aminophosphine Ligand Containing a 2,2'-Coupled Pyrrolidine-Phospholane Ring System. Synthesis and Coordination Properties with Rodium(I) and Iridium(I) Fragments / C. Bianchini; S. Cicchi; M. Peruzzini; K. M. Pietrusiewicz; A. Brandi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - STAMPA. - 1995:(1995), pp. 833-834. [10.1039/C39950000833]

A New P-Chiral Aminophosphine Ligand Containing a 2,2'-Coupled Pyrrolidine-Phospholane Ring System. Synthesis and Coordination Properties with Rodium(I) and Iridium(I) Fragments

BIANCHINI, CLAUDIO;CICCHI, STEFANO;PERUZZINI, MAURIZIO;BRANDI, ALBERTO
1995

Abstract

A new approach to the synthesis of chiral P,N-ligands containing a stereogenic phosphorus atom is reported; the synthesis, characterization and coordination properties of (PR, 2R, 3R, 2'R, 3'S, 4'S) 2[2'(3',4'-di-tert-butoxy-1'-methyltetrahydropyrrolyl)]-3-methoxy-1-phenyltetrahydrophosphole (P*-N-1), which contains a stereogenic phosphorus in addition to five contiguous stereocentres in the ligand backbone; compound P*-N-1 represents the first example of a new class of chiral P,N-ligands with the heteroatoms incorporated in two 2,2'-coupled pyrrolidine-phospholane rings.
1995
1995
833
834
C. Bianchini; S. Cicchi; M. Peruzzini; K. M. Pietrusiewicz; A. Brandi
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Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/318852
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