The cyclic voltammetric behavior of dioctadecylviologen (DV2) films of different thickness self-assembled on Ag single crystal electrodes is described. The dependence of the voltammetric behavior upon the amount of viologen deposited on Ag and upon the scan rate is explained by the interplay of the dimerization steps yielding DV2/DV, DV/DV, DV/DV0, and the two consecutive electron-transfer steps DV2/eU/DV and DV/eU/DV0.

Voltammetric behavior of dioctadecylviologen films of different thickness self-assembled on silver / A. Fernandez; M. Innocenti; R. Guidelli.. - In: JOURNAL OF ELECTROANALYTICAL CHEMISTRY. - ISSN 1572-6657. - STAMPA. - 532:(2002), pp. 237-246. [10.1016/S0022-0728(02)00864-1]

Voltammetric behavior of dioctadecylviologen films of different thickness self-assembled on silver

INNOCENTI, MASSIMO;GUIDELLI, ROLANDO
2002

Abstract

The cyclic voltammetric behavior of dioctadecylviologen (DV2) films of different thickness self-assembled on Ag single crystal electrodes is described. The dependence of the voltammetric behavior upon the amount of viologen deposited on Ag and upon the scan rate is explained by the interplay of the dimerization steps yielding DV2/DV, DV/DV, DV/DV0, and the two consecutive electron-transfer steps DV2/eU/DV and DV/eU/DV0.
2002
532
237
246
A. Fernandez; M. Innocenti; R. Guidelli.
1a - Articolo su rivista
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Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/319782
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