A novel and simple procedure for reduction of hydroxylamines to the corresponding amines by means of indium powder in aqueous media is reported. Applicability to one-pot reactions and isoxazolidine N-O bond reduction is also demonstrated. A catalytic version of the process using 2-5% In in the presence of other metals (Zn, Al) has been successfully developed.
Indium-Mediated Reduction of Hydroxylamines to Amines / S. CICCHI; M. BONANNI; F. CARDONA; J. REVUELTA; A. GOTI. - In: ORGANIC LETTERS. - ISSN 1523-7060. - STAMPA. - 5:(2003), pp. 1773-1776. [10.1021/ol034434l]
Indium-Mediated Reduction of Hydroxylamines to Amines
CICCHI, STEFANO;BONANNI, MARCO;CARDONA, FRANCESCA;GOTI, ANDREA
2003
Abstract
A novel and simple procedure for reduction of hydroxylamines to the corresponding amines by means of indium powder in aqueous media is reported. Applicability to one-pot reactions and isoxazolidine N-O bond reduction is also demonstrated. A catalytic version of the process using 2-5% In in the presence of other metals (Zn, Al) has been successfully developed.File in questo prodotto:
File | Dimensione | Formato | |
---|---|---|---|
OrgLett2003,5,1773-1776.pdf
Accesso chiuso
Tipologia:
Versione finale referata (Postprint, Accepted manuscript)
Licenza:
Tutti i diritti riservati
Dimensione
64.98 kB
Formato
Adobe PDF
|
64.98 kB | Adobe PDF | Richiedi una copia |
I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.