An easy oxidation of dihydroxyimidazolidine derivatives to nitronyl nitroxide radicals (NNRs) can be achieved using the tetra-N-propylamonium perruthenate/N-methylmorpholine N-oxide (TPAP/NMO) system. The procedure offers several advantages in terms of simplicity, yield, cost and 'green' chemistry.
TPAP/NMO system as a novel method for the synthesis of nitronyl nitroxide radicals / Gorini L.; Caneschi A.; Menichetti S.. - In: SYNLETT. - ISSN 0936-5214. - STAMPA. - 6:(2006), pp. 948-950. [10.1055/s-2006-939045]
TPAP/NMO system as a novel method for the synthesis of nitronyl nitroxide radicals
CANESCHI, ANDREA;MENICHETTI, STEFANO
2006
Abstract
An easy oxidation of dihydroxyimidazolidine derivatives to nitronyl nitroxide radicals (NNRs) can be achieved using the tetra-N-propylamonium perruthenate/N-methylmorpholine N-oxide (TPAP/NMO) system. The procedure offers several advantages in terms of simplicity, yield, cost and 'green' chemistry.
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