A solvent tune: The crystallization solvent affects the temperature and light dependence of the valence tautomeric behaviour of a 1:1 Co–dioxolene compound, thus offering a new possibility of tuning its charge distribution (see figure). This approach paves the way for the development of molecular magnetic materials whose properties may be controlled by chemical means.
Complete Direct and Reverse Optically Induced Valence Tautomeric Interconversion in a Cobalt-Dioxolene Complex / P. Dapporto; A. Dei; G. Poneti; L. Sorace. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - STAMPA. - 14:(2008), pp. 10915-10918. [10.1002/chem.200801120]
Complete Direct and Reverse Optically Induced Valence Tautomeric Interconversion in a Cobalt-Dioxolene Complex
DEI, ANDREA;PONETI, GIORDANO;SORACE, LORENZO
2008
Abstract
A solvent tune: The crystallization solvent affects the temperature and light dependence of the valence tautomeric behaviour of a 1:1 Co–dioxolene compound, thus offering a new possibility of tuning its charge distribution (see figure). This approach paves the way for the development of molecular magnetic materials whose properties may be controlled by chemical means.File | Dimensione | Formato | |
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