A solvent tune: The crystallization solvent affects the temperature and light dependence of the valence tautomeric behaviour of a 1:1 Co–dioxolene compound, thus offering a new possibility of tuning its charge distribution (see figure). This approach paves the way for the development of molecular magnetic materials whose properties may be controlled by chemical means.
Titolo: | Complete Direct and Reverse Optically Induced Valence Tautomeric Interconversion in a Cobalt-Dioxolene Complex |
Autori di Ateneo: | |
Autori: | P. Dapporto; DEI, ANDREA; PONETI, GIORDANO; SORACE, LORENZO |
Data di pubblicazione: | 2008 |
Rivista: | |
Volume: | 14 |
Pagina iniziale: | 10915 |
Pagina finale: | 10918 |
Abstract: | A solvent tune: The crystallization solvent affects the temperature and light dependence of the valence tautomeric behaviour of a 1:1 Co–dioxolene compound, thus offering a new possibility of tuning its charge distribution (see figure). This approach paves the way for the development of molecular magnetic materials whose properties may be controlled by chemical means. |
Handle: | http://hdl.handle.net/2158/344860 |
Appare nelle tipologie: | 1a - Articolo su rivista |
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