A solvent tune: The crystallization solvent affects the temperature and light dependence of the valence tautomeric behaviour of a 1:1 Co–dioxolene compound, thus offering a new possibility of tuning its charge distribution (see figure). This approach paves the way for the development of molecular magnetic materials whose properties may be controlled by chemical means.
Complete Direct and Reverse Optically Induced Valence Tautomeric Interconversion in a Cobalt-Dioxolene Complex / P. Dapporto; A. Dei; G. Poneti; L. Sorace. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - STAMPA. - 14:(2008), pp. 10915-10918. [10.1002/chem.200801120]
Complete Direct and Reverse Optically Induced Valence Tautomeric Interconversion in a Cobalt-Dioxolene Complex
DEI, ANDREA;PONETI, GIORDANO;SORACE, LORENZO
2008
Abstract
A solvent tune: The crystallization solvent affects the temperature and light dependence of the valence tautomeric behaviour of a 1:1 Co–dioxolene compound, thus offering a new possibility of tuning its charge distribution (see figure). This approach paves the way for the development of molecular magnetic materials whose properties may be controlled by chemical means.
| File | Dimensione | Formato | |
|---|---|---|---|
|
CAEJ_2008.pdf
Accesso chiuso
Tipologia:
Versione finale referata (Postprint, Accepted manuscript)
Licenza:
Tutti i diritti riservati
Dimensione
271.55 kB
Formato
Adobe PDF
|
271.55 kB | Adobe PDF | Richiedi una copia |
I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
