A bimetallic coordination polymer, (2)(infinity)[{(LNiCoII)-Co-II}(dca)(2)], has been constructed from heterobinuclear [(NiCoII)-Co-II] nodes and dicyanamido spacers [L2- is the dianion of the Schiff base resulting from the 2:1 condensation of 3-methoxysalicyladehyde with 1,3-propanediamine; L2- = NAr-propylenebis(3-methoxysalycilideneiminato)]. The intranode Co-II-Ni-II interaction was found to be ferromagnetic because of the orthogonality of the magnetic orbitals. Below 12 K, the onset of the canted ferromagnetic ordering is observed.

A 2D coordination polymer with canted ferromagnetism constructed from ferromagnetic [(NiCoII)-Co-II] nodes / D. G. Branzea; L. Sorace; C. Maxim; M. Andruh; A. Caneschi. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - STAMPA. - 47:(2008), pp. 6590-6592. [10.1021/ic800946v]

A 2D coordination polymer with canted ferromagnetism constructed from ferromagnetic [(NiCoII)-Co-II] nodes

SORACE, LORENZO;CANESCHI, ANDREA
2008

Abstract

A bimetallic coordination polymer, (2)(infinity)[{(LNiCoII)-Co-II}(dca)(2)], has been constructed from heterobinuclear [(NiCoII)-Co-II] nodes and dicyanamido spacers [L2- is the dianion of the Schiff base resulting from the 2:1 condensation of 3-methoxysalicyladehyde with 1,3-propanediamine; L2- = NAr-propylenebis(3-methoxysalycilideneiminato)]. The intranode Co-II-Ni-II interaction was found to be ferromagnetic because of the orthogonality of the magnetic orbitals. Below 12 K, the onset of the canted ferromagnetic ordering is observed.
2008
47
6590
6592
D. G. Branzea; L. Sorace; C. Maxim; M. Andruh; A. Caneschi
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Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/344868
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