A new inorganic-organic hybrid [VO(pcp)], where pep is the P,P'diphenylmethylenediphosphinate ligand, has been hydrothermally synthesized and structurally characterized. The X-ray analysis revealed an undulated 2D-layered structure, where VO5 moieties are connected through bridging phosphinate groups. Magnetic measurements in the range 300-2 K have shown a weak ferromagnetic interaction between vanadyl groups.
Hydrothermal synthesis and structural characterization of a new 2D-layered vanadium diphosphinate: [VO(O-2(C6H5)PCH2P(C6H5)O-2)] / F. Costantino; S. Midollini; A. Orlandini; L. Sorace. - In: INORGANIC CHEMISTRY COMMUNICATIONS. - ISSN 1387-7003. - STAMPA. - 9:(2006), pp. 591-594. [10.1016/j.inoche.2006.03.007]
Hydrothermal synthesis and structural characterization of a new 2D-layered vanadium diphosphinate: [VO(O-2(C6H5)PCH2P(C6H5)O-2)]
SORACE, LORENZO
2006
Abstract
A new inorganic-organic hybrid [VO(pcp)], where pep is the P,P'diphenylmethylenediphosphinate ligand, has been hydrothermally synthesized and structurally characterized. The X-ray analysis revealed an undulated 2D-layered structure, where VO5 moieties are connected through bridging phosphinate groups. Magnetic measurements in the range 300-2 K have shown a weak ferromagnetic interaction between vanadyl groups.
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