Getting in tune: A material that undergoes valence tautomerism was obtained by tuning the electronic properties of a cobalt–polyoxolene complex (shown schematically) which contains a tripositive metal ion acting as an ancillary counterpart. The tautomerism, which can be thermally or light induced, is quantitative upon irradiation at 617 nm.
Thermally and light-induced valence tautomeric transition in a dinuclear cobalt-tetraoxolene complex / C. Carbonera; A. Dei; J. F. Letard; C. Sangregorio; L. Sorace. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 43:(2004), pp. 3136-3138. [10.1002/anie.200453944]
Thermally and light-induced valence tautomeric transition in a dinuclear cobalt-tetraoxolene complex
CARBONERA, CHIARA;DEI, ANDREA;SANGREGORIO, CLAUDIO;SORACE, LORENZO
2004
Abstract
Getting in tune: A material that undergoes valence tautomerism was obtained by tuning the electronic properties of a cobalt–polyoxolene complex (shown schematically) which contains a tripositive metal ion acting as an ancillary counterpart. The tautomerism, which can be thermally or light induced, is quantitative upon irradiation at 617 nm.
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