The potassium salt of the triphenylphosphine oxide adduct of bis(tetrachlorocatecholate)mangnnese(III) complex reacts with O-2 in the presence of K+-sequestering agents at room temperature in MeCN resulting in the formation of the corresponding Mn-IV-tris( catecholate) species.
Counter cation-controlled air oxidation of manganese derivatives of tetrachlorocatechol / R. Ruiz; A. Caneschi; D. Gatteschi; C. Sangregorio; L. Sorace; M. Vazquez. - In: INORGANIC CHEMISTRY COMMUNICATIONS. - ISSN 1387-7003. - STAMPA. - 3:(2000), pp. 76-79. [S1387-7003(00)00010-1]
Counter cation-controlled air oxidation of manganese derivatives of tetrachlorocatechol
CANESCHI, ANDREA;GATTESCHI, DANTE;SANGREGORIO, CLAUDIO;SORACE, LORENZO;
2000
Abstract
The potassium salt of the triphenylphosphine oxide adduct of bis(tetrachlorocatecholate)mangnnese(III) complex reacts with O-2 in the presence of K+-sequestering agents at room temperature in MeCN resulting in the formation of the corresponding Mn-IV-tris( catecholate) species.
File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
ICC_00.pdf
Accesso chiuso
Descrizione: ICC_00
Tipologia:
Pdf editoriale (Version of record)
Licenza:
Open Access
Dimensione
146.53 kB
Formato
Adobe PDF
|
146.53 kB | Adobe PDF | Richiedi una copia |
I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
