Ten long-chain saturated and unsaturated alcohols were reacted with the ionic species [C(2) H(2) N](+) and [C(3) H(4) N](+) generated by ionization of acetonitrile into an ion trap. The mass spectra of the compounds under investigation show the formation of [M -H](+), [M + C(2) H(2) N](+) and [M + C(2) H(4) N](+) ions in the case of saturated alcohols, whereas for monounsaturated and polyunsaturated derivatives additional peaks corresponding to [M + H](+) and [M + H -H(2) O](+) are observed. The reaction mechanisms were investigated by means of D- and (13)C-labelled acetonitrile. Collisional experiments were performed on the [M + C(3) H(4) N](+) species from the polyunsaturated alcohols in order to identify any possibly diagnostic fragments for the identification of the double bond positions.

Reactions of ionic species from acetonitrile with long-chain saturated and unsaturated alcohols / G. Moneti; G. Pieraccini; D. Favretto; P. Traldi. - In: JOURNAL OF MASS SPECTROMETRY. - ISSN 1076-5174. - STAMPA. - 34:(1999), pp. 1354-1360.

Reactions of ionic species from acetonitrile with long-chain saturated and unsaturated alcohols

MONETI, GLORIANO;PIERACCINI, GIUSEPPE;
1999

Abstract

Ten long-chain saturated and unsaturated alcohols were reacted with the ionic species [C(2) H(2) N](+) and [C(3) H(4) N](+) generated by ionization of acetonitrile into an ion trap. The mass spectra of the compounds under investigation show the formation of [M -H](+), [M + C(2) H(2) N](+) and [M + C(2) H(4) N](+) ions in the case of saturated alcohols, whereas for monounsaturated and polyunsaturated derivatives additional peaks corresponding to [M + H](+) and [M + H -H(2) O](+) are observed. The reaction mechanisms were investigated by means of D- and (13)C-labelled acetonitrile. Collisional experiments were performed on the [M + C(3) H(4) N](+) species from the polyunsaturated alcohols in order to identify any possibly diagnostic fragments for the identification of the double bond positions.
1999
34
1354
1360
G. Moneti; G. Pieraccini; D. Favretto; P. Traldi
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Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/348557
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