The surface sensitivity of X-ray Magnetic Circular Dichroism in extreme conditions is exploited to investigate the first layers of bulk single-molecule magnets (SMM). Striking differences emerge between two classes of SMM with different structural constraints, thus highlighting the importance of molecular design in the realization of molecular spintronic devices.
X-Ray Magnetic Circular Dichroism Picks out Single-Molecule Magnets Suitable for Nanodevices / M. Mannini; F. Pineider; P. Sainctavit; L. Joly; A. Fraile-Rodrıguez; M.A. Arrio; C. Cartier dit Moulin; W. Wernsdorfer; A. Cornia; D. Gatteschi; R. Sessoli. - In: ADVANCED MATERIALS. - ISSN 0935-9648. - STAMPA. - 21:(2009), pp. 167-171. [10.1002/adma.200801883]
X-Ray Magnetic Circular Dichroism Picks out Single-Molecule Magnets Suitable for Nanodevices
MANNINI, MATTEO;PINEIDER, FRANCESCO;GATTESCHI, DANTE;SESSOLI, ROBERTA
2009
Abstract
The surface sensitivity of X-ray Magnetic Circular Dichroism in extreme conditions is exploited to investigate the first layers of bulk single-molecule magnets (SMM). Striking differences emerge between two classes of SMM with different structural constraints, thus highlighting the importance of molecular design in the realization of molecular spintronic devices.
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