A (2-aminoarenethiolato)copper(I) complex has been used as an efficient catalyst (1 mol-%) for the copper-catalysed Huisgen reaction (CuAAC) of azides and terminal alkynes in an organic solvent. The reaction was also extremely effective in CH2Cl2 allowing the complete decoration of dendrimeric scaffolds.
An Efficient (2-Aminoarenethiolato)copper(I) Complex for theCopper-Catalysed Huisgen Reaction (CuAAC) / P. Fabbrizzi; S. Cicchi; A. Brandi; E. Sperotto; G. van Koten. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - STAMPA. - 2009:(2009), pp. 5423-5430. [10.1002/ejoc.200900779]
An Efficient (2-Aminoarenethiolato)copper(I) Complex for theCopper-Catalysed Huisgen Reaction (CuAAC)
FABBRIZZI, PIERANGELO;CICCHI, STEFANO;BRANDI, ALBERTO;
2009
Abstract
A (2-aminoarenethiolato)copper(I) complex has been used as an efficient catalyst (1 mol-%) for the copper-catalysed Huisgen reaction (CuAAC) of azides and terminal alkynes in an organic solvent. The reaction was also extremely effective in CH2Cl2 allowing the complete decoration of dendrimeric scaffolds.
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