A new method for protecting alcohols as tert-butyl ethers is reported. The reaction is performed in tert-butyl acetate in the presence of a catalytic amount of HClO4. The process is extremely efficient and primary and secondary alcohols as well as diols are protected under very mild conditions. Remarkably, tert-butyl acetate can be easily recovered after the workup of the reaction and recycled.
A New, practical, and efficient method for protecting alcohols as tert-butyl ethers / A.Barge; E.G.Occhiato; C.Prandi; D.Scarpi; S.Tabasso; P.Venturello. - In: SYNLETT. - ISSN 0936-5214. - STAMPA. - ...:(2010), pp. 812-816. [10.1055/s-0029-1219360]
A New, practical, and efficient method for protecting alcohols as tert-butyl ethers
OCCHIATO, ERNESTO GIOVANNI;SCARPI, DINA;
2010
Abstract
A new method for protecting alcohols as tert-butyl ethers is reported. The reaction is performed in tert-butyl acetate in the presence of a catalytic amount of HClO4. The process is extremely efficient and primary and secondary alcohols as well as diols are protected under very mild conditions. Remarkably, tert-butyl acetate can be easily recovered after the workup of the reaction and recycled.
| File | Dimensione | Formato | |
|---|---|---|---|
|
Barge SYNLETT 2010.pdf
Accesso chiuso
Descrizione: testo
Tipologia:
Pdf editoriale (Version of record)
Licenza:
Tutti i diritti riservati
Dimensione
120.45 kB
Formato
Adobe PDF
|
120.45 kB | Adobe PDF | Richiedi una copia |
I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
