Assembly of the tetranuclear oxomanganese(III) acetato cluster [Mn4O2(O2CMe)(7)(phen)(2)](BF4) from the dinuclear oxo-di(acetato)bridged manganese(III) species [Mn2O(O2CMe)(2)(H2O)(2)(phen)(2)](BF4)(2) . 3H(2)O in aqueous/acetic acid MeOH solution occurs via the new 'dimer of dimers' Mn-III complex [Mn2O(O2CMe)(3)(H2O)(phen)(2)](BF4) . MeOH possesing an unprecedent [Mn-4(mu-O)(2)(mu-O2Me)(4) (mu-(OH2O2CMe)-O-...)(2)] core.
A novel dimer of oxo-di(acetato)-bridged manganese(III) dimers complex of potential biological significance / Ruiz R; Sangregorio C; Caneschi A; Rossi P; Gaspar AB; Real JA; Munoz MC. - In: INORGANIC CHEMISTRY COMMUNICATIONS. - ISSN 1387-7003. - STAMPA. - 3:(2000), pp. 361-367. [10.1016/S1387-7003(00)00099-X]
A novel dimer of oxo-di(acetato)-bridged manganese(III) dimers complex of potential biological significance
SANGREGORIO, CLAUDIO;CANESCHI, ANDREA;ROSSI, PATRIZIA;
2000
Abstract
Assembly of the tetranuclear oxomanganese(III) acetato cluster [Mn4O2(O2CMe)(7)(phen)(2)](BF4) from the dinuclear oxo-di(acetato)bridged manganese(III) species [Mn2O(O2CMe)(2)(H2O)(2)(phen)(2)](BF4)(2) . 3H(2)O in aqueous/acetic acid MeOH solution occurs via the new 'dimer of dimers' Mn-III complex [Mn2O(O2CMe)(3)(H2O)(phen)(2)](BF4) . MeOH possesing an unprecedent [Mn-4(mu-O)(2)(mu-O2Me)(4) (mu-(OH2O2CMe)-O-...)(2)] core.
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