The synergistic action of the different binding groups of the polyfunctional HL receptor leads to the recognition of ADP over ATP in water, with a selectivity coefficient of up to 116, a phenomenon which is unprecedented in the context of synthetic receptors in water. The recognition is mostly due to the good matching between H3L2+ and the protonated forms of ADP.
Molecular recognition of ADP over ATP in aqueous solution by a polyammonium receptor containing a pyrimidine residue / P.Arranz Mascaros; C.Bazzicalupi; A.Bianchi; C.Giorgi; M.D.Gutierrez Valero; R.Lopez Garzon; M.L. Godino Salido; B.Valtancoli. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 47:(2011), pp. 2814-2816. [10.1039/c0cc05054g]
Molecular recognition of ADP over ATP in aqueous solution by a polyammonium receptor containing a pyrimidine residue.
BAZZICALUPI, CARLA;BIANCHI, ANTONIO;GIORGI, CLAUDIA;VALTANCOLI, BARBARA
2011
Abstract
The synergistic action of the different binding groups of the polyfunctional HL receptor leads to the recognition of ADP over ATP in water, with a selectivity coefficient of up to 116, a phenomenon which is unprecedented in the context of synthetic receptors in water. The recognition is mostly due to the good matching between H3L2+ and the protonated forms of ADP.
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