The pi -connectivity of a bis(semiquinone) ligand enforces ferromagnetic coupling between the two semiquinone halves of the molecule. Using the ligand in connection with paramagnetic metal ions lends to complexes with S = 3 (M = Ni-II), S = 2 (M = Cu-II), and S = 2 (M = Cr-III) ground states.
FERROMAGNETICALLY COUPLED BIS(SEMIQUINONE) LIGAND ENFORCES HIGH-SPIN GROUND STATES IN BIS-METAL COMPLEXES / A. DEI; A. CANESCHI; L. SORACE; H. LEE; D. SHULTZ. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - STAMPA. - 40:(2001), pp. 408-408. [10.1021/ic000440r]
FERROMAGNETICALLY COUPLED BIS(SEMIQUINONE) LIGAND ENFORCES HIGH-SPIN GROUND STATES IN BIS-METAL COMPLEXES
DEI, ANDREA;CANESCHI, ANDREA;SORACE, LORENZO;
2001
Abstract
The pi -connectivity of a bis(semiquinone) ligand enforces ferromagnetic coupling between the two semiquinone halves of the molecule. Using the ligand in connection with paramagnetic metal ions lends to complexes with S = 3 (M = Ni-II), S = 2 (M = Cu-II), and S = 2 (M = Cr-III) ground states.
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