Optically pure phenylseleno-(S)-2-p-tolylsulfinylbenzylcarbanions react with (S)-N-2-p-tolylsulfinylimines derived from aliphatic and aromatic aldehydes in a highly stereoselective manner affording bis-sulfinylselenoamines, easily transformed into 1-phenyl, 2-aryl (or alkyl)-2-phenylseleno ethylamines by subsequent reactions, which were treatment reactions with t-BuLi and TFA
Synthesis of enantiomerically pure 1,2-disubstituted 2-selenoamines / E. Torrente; J. L. García Ruano; A. M. Martín Castro; A. Degl`Innocenti; A. Capperucci; L. Frateschi. - In: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. - ISSN 1042-6507. - ELETTRONICO. - 186:(2011), pp. 1268-1273. [10.1080/10426507.2010.536062]
Synthesis of enantiomerically pure 1,2-disubstituted 2-selenoamines
DEGL'INNOCENTI, ALESSANDRO;CAPPERUCCI, ANTONELLA;
2011
Abstract
Optically pure phenylseleno-(S)-2-p-tolylsulfinylbenzylcarbanions react with (S)-N-2-p-tolylsulfinylimines derived from aliphatic and aromatic aldehydes in a highly stereoselective manner affording bis-sulfinylselenoamines, easily transformed into 1-phenyl, 2-aryl (or alkyl)-2-phenylseleno ethylamines by subsequent reactions, which were treatment reactions with t-BuLi and TFA
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