Reaction of acyl chlorides with phenylselenotrimethyl-silane promoted by TBAF afforded a mild general access to selenolesters in good yields. When acyl chlorides were reacted with bis(trimethylsilyl)selenide (HMDSS) in 2:1 or 1:1 ratio a selective entry to selenoanhydrides or diacyl diselenides respectively was obtained.
Organoselenosilanes mediated selective mild access to selenolesters, selenoanhydrides and diacyl diselenides / A. Capperucci; A. Degl’Innocenti; C. Tiberi. - In: SYNLETT. - ISSN 0936-5214. - ELETTRONICO. - ..:(2011), pp. 2248-2252. [10.1055/s-0030-1261195]
Organoselenosilanes mediated selective mild access to selenolesters, selenoanhydrides and diacyl diselenides
CAPPERUCCI, ANTONELLA;DEGL'INNOCENTI, ALESSANDRO;TIBERI, CATERINA
2011
Abstract
Reaction of acyl chlorides with phenylselenotrimethyl-silane promoted by TBAF afforded a mild general access to selenolesters in good yields. When acyl chlorides were reacted with bis(trimethylsilyl)selenide (HMDSS) in 2:1 or 1:1 ratio a selective entry to selenoanhydrides or diacyl diselenides respectively was obtained.
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