EVALUATING THE MAGNETIC ANISOTROPY IN MOLECULAR RARE EARTH COMPOUNDS. GADOLINIUM DERIVATIVES WITH SEMIQUINONE RADICAL AND DIAMAGNETIC ANALOGUES

Caneschi, A.; Gatteschi, D.; Dei, A.; Sorace, L.; Massa, C.; Pardi, L.; Pousserau, L.

doi:10.1016/S0009-2614(03)00346-4

The magnetic anisotropy of two Gd(III) derivatives has been investigated by multifrequency HF-EPR spectroscopy. The reliability of the method of diamagnetic substitution for the estimation of crystal field effects in rare earth compounds is discussed on the basis of the experimental results and of the estimation of the dipolar contribution to the anisotropy

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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2158/5671

Titolo:	EVALUATING THE MAGNETIC ANISOTROPY IN MOLECULAR RARE EARTH COMPOUNDS. GADOLINIUM DERIVATIVES WITH SEMIQUINONE RADICAL AND DIAMAGNETIC ANALOGUES
Autori interni:	CANESCHI, ANDREA GATTESCHI, DANTE DEI, ANDREA SORACE, LORENZO PARDI, LEO
Autori:	A. CANESCHI; D. GATTESCHI; A. DEI; L. SORACE; C. MASSA; L. PARDI; L. POUSSERAU
Data di pubblicazione:	2003
Rivista:	CHEMICAL PHYSICS LETTERS
Volume:	371
Pagina iniziale:	694
Pagina finale:	699
Abstract:	The magnetic anisotropy of two Gd(III) derivatives has been investigated by multifrequency HF-EPR spectroscopy. The reliability of the method of diamagnetic substitution for the estimation of crystal field effects in rare earth compounds is discussed on the basis of the experimental results and of the estimation of the dipolar contribution to the anisotropy
Handle:	http://hdl.handle.net/2158/5671
Appare nelle tipologie:	1a - Articolo su rivista

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