EVALUATING THE MAGNETIC ANISOTROPY IN MOLECULAR RARE EARTH COMPOUNDS. GADOLINIUM DERIVATIVES WITH SEMIQUINONE RADICAL AND DIAMAGNETIC ANALOGUES

Caneschi, Andrea; Gatteschi, Dante; Dei, Andrea; Sorace, Lorenzo; Massa, C.; Pardi, Leo; Pousserau, L.

doi:10.1016/S0009-2614(03)00346-4

The magnetic anisotropy of two Gd(III) derivatives has been investigated by multifrequency HF-EPR spectroscopy. The reliability of the method of diamagnetic substitution for the estimation of crystal field effects in rare earth compounds is discussed on the basis of the experimental results and of the estimation of the dipolar contribution to the anisotropy

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Titolo:	EVALUATING THE MAGNETIC ANISOTROPY IN MOLECULAR RARE EARTH COMPOUNDS. GADOLINIUM DERIVATIVES WITH SEMIQUINONE RADICAL AND DIAMAGNETIC ANALOGUES
Autori di Ateneo:	CANESCHI, ANDREA GATTESCHI, DANTE DEI, ANDREA SORACE, LORENZO C. MASSA PARDI, LEO L. POUSSERAU mostra contributor esterni nascondi contributor esterni
Autori:	CANESCHI, ANDREA; GATTESCHI, DANTE; DEI, ANDREA; SORACE, LORENZO; C. MASSA; PARDI, LEO; L. POUSSERAU
Anno di registrazione:	2003
Rivista:	CHEMICAL PHYSICS LETTERS
Volume:	371
Pagina iniziale:	694
Pagina finale:	699
Abstract:	The magnetic anisotropy of two Gd(III) derivatives has been investigated by multifrequency HF-EPR spectroscopy. The reliability of the method of diamagnetic substitution for the estimation of crystal field effects in rare earth compounds is discussed on the basis of the experimental results and of the estimation of the dipolar contribution to the anisotropy
Handle:	http://hdl.handle.net/2158/5671
Appare nelle tipologie:	1a - Articolo su rivista

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