Tunable far-infrared spectroscopy was applied to the study of small asymmetry doublings in the ground vibrational, ground torsional state of CH3OH. For the first time splittings of K = 6 states were measured. The splitting constant was found to be S(6) = 9(1) × 10−19 MHz, corresponding to a splitting of 360(35) KHz for J = 29 and 240(25) kHz for J = 28.
Frequency measurement of the K = 6 asymmetry splittings in CH3OH / L.R. Zink;K.M. Evenson;D.A. Jennings;G. Moruzzi;M. Inguscio. - In: JOURNAL OF MOLECULAR SPECTROSCOPY. - ISSN 0022-2852. - STAMPA. - 127:(1988), pp. 44-50. [10.1016/0022-2852(88)90006-9]
Frequency measurement of the K = 6 asymmetry splittings in CH3OH
INGUSCIO, MASSIMO
1988
Abstract
Tunable far-infrared spectroscopy was applied to the study of small asymmetry doublings in the ground vibrational, ground torsional state of CH3OH. For the first time splittings of K = 6 states were measured. The splitting constant was found to be S(6) = 9(1) × 10−19 MHz, corresponding to a splitting of 360(35) KHz for J = 29 and 240(25) kHz for J = 28.
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