Stark measurement of the electric dipole moment components of H16O35Cl is performed with a tunable far-infrared spectrometer at the European Laboratory for Nonlinear Spectroscopy, Firenze, Italy. Two pure rotational transitions are analyzed, namely, the 11,1–00,0 at approximately 628 GHz and the asymmetry doublet 43,2–32,1, 43,1–32,2 at approximately 3.1 THz. The values obtained for μa and μb represent the first reported measurement of dipole moments from far-infrared transitions with an accuracy up to several parts in 104.
Precise measurement of molecular dipole moments with a tunable far-infrared Stark spectrometer: application to HOCl / G. Modugno;P. De Natale;M. Bellini;M. Inguscio;G. Di Lonardo;L. Fusina;J. Vander Auwera. - In: JOURNAL OF THE OPTICAL SOCIETY OF AMERICA. B, OPTICAL PHYSICS. - ISSN 0740-3224. - STAMPA. - 13:(1996), pp. 1645-1649. [10.1364/JOSAB.13.001645]
Precise measurement of molecular dipole moments with a tunable far-infrared Stark spectrometer: application to HOCl
MODUGNO, GIOVANNI;DE NATALE, PAOLO;BELLINI, MARCO;INGUSCIO, MASSIMO;
1996
Abstract
Stark measurement of the electric dipole moment components of H16O35Cl is performed with a tunable far-infrared spectrometer at the European Laboratory for Nonlinear Spectroscopy, Firenze, Italy. Two pure rotational transitions are analyzed, namely, the 11,1–00,0 at approximately 628 GHz and the asymmetry doublet 43,2–32,1, 43,1–32,2 at approximately 3.1 THz. The values obtained for μa and μb represent the first reported measurement of dipole moments from far-infrared transitions with an accuracy up to several parts in 104.
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