Single-crystal e.s.r., spectra of the 1:1 adduct of copper(II) hexafluoro-acetylacetonate and the free radical 2,4,4,5,5-pentamethyl-3-oxido-4,5-dihydroimidazol-1-oxyl (NITMe), Cu(hfac)2(NITMe), have been recorded at room temperature at both X- and Q-band frequencies. At X-band frequency the liquid-helium-temperature spectra have also been collected. Linewidth analysis has been performed by considering the dipolar and anisotropic spin–spin interactions together, indicating that in the present compound the D tensor relative to the nearest-neighbour radical copper(II) interaction must be axial, with the unique axis approximately parallel to the Cu—O (nitroxide) bond. The low-temperature spectra show a g shift due to effects of short-range order effects.
Electron spin resonance spectra of a ferromagnetic alternating spin chain (S 1=�, S 2=�) / Andrea Caneschi;Dante Gatteschi;Claudia Zanchini;Paul Rey. - In: JOURNAL OF THE CHEMICAL SOCIETY. FARADAY TRANSACTIONS I. - ISSN 0300-9599. - STAMPA. - 83:(1987), pp. 3603-3612. [10.1039/f19878303603]
Electron spin resonance spectra of a ferromagnetic alternating spin chain (S 1=�, S 2=�)
CANESCHI, ANDREA;GATTESCHI, DANTE;
1987
Abstract
Single-crystal e.s.r., spectra of the 1:1 adduct of copper(II) hexafluoro-acetylacetonate and the free radical 2,4,4,5,5-pentamethyl-3-oxido-4,5-dihydroimidazol-1-oxyl (NITMe), Cu(hfac)2(NITMe), have been recorded at room temperature at both X- and Q-band frequencies. At X-band frequency the liquid-helium-temperature spectra have also been collected. Linewidth analysis has been performed by considering the dipolar and anisotropic spin–spin interactions together, indicating that in the present compound the D tensor relative to the nearest-neighbour radical copper(II) interaction must be axial, with the unique axis approximately parallel to the Cu—O (nitroxide) bond. The low-temperature spectra show a g shift due to effects of short-range order effects.File | Dimensione | Formato | |
---|---|---|---|
JCS_1987.pdf
Accesso chiuso
Tipologia:
Versione finale referata (Postprint, Accepted manuscript)
Licenza:
Tutti i diritti riservati
Dimensione
4.41 MB
Formato
Adobe PDF
|
4.41 MB | Adobe PDF | Richiedi una copia |
I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.