The magnetic properties of novel linear chain compounds containing lanthanide(III) ions (gadolinium, europium) coupled to stable nitronyl-nitroxide radicals are reported. The metal ions and the radicals are regularly alternating along the chain. The magnetic behaviors appears to be dominated by antiferromagnetic interactions between the radicals.
MAGNETIC PROPERTIES OF LINEAR CHAIN COMPOUNDS FORMED BY LANTHANIDE(III) IONS AND NITRONYL-NITROXIDE RADICALS / C. Benelli;A. Caneschi;D. Gatteschi;L. Pardi;P. Rey. - In: JOURNAL DE PHYSIQUE. COLLOQUE. - ISSN 0449-1947. - STAMPA. - 49:(1988), pp. C8-861-C8-862. [10.1051/jphyscol:19888389]
MAGNETIC PROPERTIES OF LINEAR CHAIN COMPOUNDS FORMED BY LANTHANIDE(III) IONS AND NITRONYL-NITROXIDE RADICALS
BENELLI, CRISTIANO;CANESCHI, ANDREA;GATTESCHI, DANTE;PARDI, LEO;
1988
Abstract
The magnetic properties of novel linear chain compounds containing lanthanide(III) ions (gadolinium, europium) coupled to stable nitronyl-nitroxide radicals are reported. The metal ions and the radicals are regularly alternating along the chain. The magnetic behaviors appears to be dominated by antiferromagnetic interactions between the radicals.
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