The coordination chemistry of bidentate nitroxides is reviewed. Practical indications for the synthesis of extended ferro-or ferrimagnetic chains with high-spin ground states consisting of alternating transition-metal ions and bidentate nitroxide radicals are reported.
Synthesis of High-Spin Molecular Species Using Nitroxide Organic Radicals and Transition Metal Ions / Paul Rey;Jean Laugier;Andrea Caneschi;Dante Gatteschi. - In: MOLECULAR CRYSTALS AND LIQUID CRYSTALS INCORPORATING NONLINEAR OPTICS. - ISSN 1044-1859. - STAMPA. - 176:(1989), pp. 337-345. [10.1080/00268948908037492]
Synthesis of High-Spin Molecular Species Using Nitroxide Organic Radicals and Transition Metal Ions
CANESCHI, ANDREA;GATTESCHI, DANTE
1989
Abstract
The coordination chemistry of bidentate nitroxides is reviewed. Practical indications for the synthesis of extended ferro-or ferrimagnetic chains with high-spin ground states consisting of alternating transition-metal ions and bidentate nitroxide radicals are reported.
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