Some oligo- or polyamides containing several hydroxyl groups were synthesized in order to obtain new water-soluble compounds with a high affinity for polar materials as wood, paper, and natural fibers. The interest for the synthetic procedures is the use of renewable sources as starting compounds. In fact natural compounds or their derivatives, as L-tartaric acid, D(þ)-glucaric acid and a,a-trehaluronic acid, were used as dicarboxylic acids in the polycondensation reactions, in order to obtain several functionalized oligoamides. All the compounds obtained in this study were characterized through FTIR and NMR spectroscopy. The oligoamides, water-soluble and not provided with high-molecular weights, were tested as wood consolidants. Physical properties like hygroscopicity of stabilized wood, volume shrinkage, density, and basic density were evaluated on the treated samples and compared with those obtained in the same conditions for an untreated archeological sample and a recent wood sample.

Synthesis of hydroxylated oligoamides for their use in wood conservation / G. Cipriani; A. Salvini; M. Fioravanti; G. Di Giulio ;M. Malavolti. - In: JOURNAL OF APPLIED POLYMER SCIENCE. - ISSN 1097-4628. - STAMPA. - 127:(2013), pp. 420-431. [10.1002/APP.37678]

Synthesis of hydroxylated oligoamides for their use in wood conservation

SALVINI, ANTONELLA;FIORAVANTI, MARCO;DI GIULIO, GIUSEPPINA;
2013

Abstract

Some oligo- or polyamides containing several hydroxyl groups were synthesized in order to obtain new water-soluble compounds with a high affinity for polar materials as wood, paper, and natural fibers. The interest for the synthetic procedures is the use of renewable sources as starting compounds. In fact natural compounds or their derivatives, as L-tartaric acid, D(þ)-glucaric acid and a,a-trehaluronic acid, were used as dicarboxylic acids in the polycondensation reactions, in order to obtain several functionalized oligoamides. All the compounds obtained in this study were characterized through FTIR and NMR spectroscopy. The oligoamides, water-soluble and not provided with high-molecular weights, were tested as wood consolidants. Physical properties like hygroscopicity of stabilized wood, volume shrinkage, density, and basic density were evaluated on the treated samples and compared with those obtained in the same conditions for an untreated archeological sample and a recent wood sample.
2013
127
420
431
G. Cipriani; A. Salvini; M. Fioravanti; G. Di Giulio ;M. Malavolti
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Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/648016
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