The X-ray structure of Cu(en)3Cl2 · 0.75 en has been solved as a model of frozen Jahn-Teller distortions experienced by Cu(en)2+3 complexes. The distorted chromophores are elongated octahedra though the crystal g values simulate a compressed distortion.
X-ray and ESR investigation of an elongated octahedral tris-(1, 2-diaminoethane) copper (II) complex / I. Bertini;P. Dapporto;D. Gatteschi;A. Scozzafava. - In: SOLID STATE COMMUNICATIONS. - ISSN 0038-1098. - STAMPA. - 26:(1978), pp. 749-751. [10.1016/0038-1098(78)90734-2]
X-ray and ESR investigation of an elongated octahedral tris-(1, 2-diaminoethane) copper (II) complex
BERTINI, IVANO;DAPPORTO, PAOLO;GATTESCHI, DANTE;SCOZZAFAVA, ANDREA
1978
Abstract
The X-ray structure of Cu(en)3Cl2 · 0.75 en has been solved as a model of frozen Jahn-Teller distortions experienced by Cu(en)2+3 complexes. The distorted chromophores are elongated octahedra though the crystal g values simulate a compressed distortion.
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