X-ray structure of [N(n-C4H94)][CoBr3(quinoline)] shows that the complex possesses a symmetry near to C3, the Co-N bond direction being the pseudo C3 axis. The single crystal spectra are largely anisotropic: g1=6.31, g2=2.33, g3=1.61. g3, makes an angle of 2̃0° with Co-N. These results are easily interpreted using a symmetry iView the MathML source dependent Ligand Field Model. The application of the model to the calculation of the cobalt hyperfine coupling constant is also shown.

ESR spectra of low-symmetry high-spin cobalt(II) complexes / A. Bencini;C. Benelli;D. Gatteschi;C. Zanchini. - In: JOURNAL OF MOLECULAR STRUCTURE. - ISSN 0022-2860. - STAMPA. - 60:(1980), pp. 401-404. [10.1016/0022-2860(80)80098-6]

ESR spectra of low-symmetry high-spin cobalt(II) complexes

BENCINI, ALESSANDRO;BENELLI, CRISTIANO;GATTESCHI, DANTE;
1980

Abstract

X-ray structure of [N(n-C4H94)][CoBr3(quinoline)] shows that the complex possesses a symmetry near to C3, the Co-N bond direction being the pseudo C3 axis. The single crystal spectra are largely anisotropic: g1=6.31, g2=2.33, g3=1.61. g3, makes an angle of 2̃0° with Co-N. These results are easily interpreted using a symmetry iView the MathML source dependent Ligand Field Model. The application of the model to the calculation of the cobalt hyperfine coupling constant is also shown.
1980
60
401
404
A. Bencini;C. Benelli;D. Gatteschi;C. Zanchini
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/654581
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 8
  • ???jsp.display-item.citation.isi??? ND
social impact