X-ray structure of [N(n-C4H94)][CoBr3(quinoline)] shows that the complex possesses a symmetry near to C3, the Co-N bond direction being the pseudo C3 axis. The single crystal spectra are largely anisotropic: g1=6.31, g2=2.33, g3=1.61. g3, makes an angle of 2̃0° with Co-N. These results are easily interpreted using a symmetry iView the MathML source dependent Ligand Field Model. The application of the model to the calculation of the cobalt hyperfine coupling constant is also shown.
ESR spectra of low-symmetry high-spin cobalt(II) complexes / A. Bencini;C. Benelli;D. Gatteschi;C. Zanchini. - In: JOURNAL OF MOLECULAR STRUCTURE. - ISSN 0022-2860. - STAMPA. - 60:(1980), pp. 401-404. [10.1016/0022-2860(80)80098-6]
ESR spectra of low-symmetry high-spin cobalt(II) complexes
BENCINI, ALESSANDRO;BENELLI, CRISTIANO;GATTESCHI, DANTE;
1980
Abstract
X-ray structure of [N(n-C4H94)][CoBr3(quinoline)] shows that the complex possesses a symmetry near to C3, the Co-N bond direction being the pseudo C3 axis. The single crystal spectra are largely anisotropic: g1=6.31, g2=2.33, g3=1.61. g3, makes an angle of 2̃0° with Co-N. These results are easily interpreted using a symmetry iView the MathML source dependent Ligand Field Model. The application of the model to the calculation of the cobalt hyperfine coupling constant is also shown.
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