The single crystal ESR spectrum of the square pyramidal iodo[difluoro[3,3′-(trimethylenedinitrilo)-bis(2-butanoneoximato)] borato] copper(II), Cu(cyclops)I, complex diluted into the nickel(II) lattice has been recorded. The spin Hamiltonian parameters (g1 = 2.05, g2 = 2.07, g3 = 2.18, A3 = 190 × 10−4 cm−1) have been interpreted using a symmetry independent angular overlap model. This analysis shows that the in-plane field is fairly strong thus explaining the observed diamagnetism of the Ni(cyclops)X adducts.
ESR spectra of the square pyramidal iodo [difluoro[3,3′-(trimethylenedinitrilo)-bis(2-butanone oximato)] borato] copper(II) complex / A. Bencini;D. Gatteschi;C. Zanchini;M. Wicholas. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 49:(1981), pp. 1-4. [10.1016/S0020-1693(00)90449-3]
ESR spectra of the square pyramidal iodo [difluoro[3,3′-(trimethylenedinitrilo)-bis(2-butanone oximato)] borato] copper(II) complex
BENCINI, ALESSANDRO;GATTESCHI, DANTE;
1981
Abstract
The single crystal ESR spectrum of the square pyramidal iodo[difluoro[3,3′-(trimethylenedinitrilo)-bis(2-butanoneoximato)] borato] copper(II), Cu(cyclops)I, complex diluted into the nickel(II) lattice has been recorded. The spin Hamiltonian parameters (g1 = 2.05, g2 = 2.07, g3 = 2.18, A3 = 190 × 10−4 cm−1) have been interpreted using a symmetry independent angular overlap model. This analysis shows that the in-plane field is fairly strong thus explaining the observed diamagnetism of the Ni(cyclops)X adducts.I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.