Depth-Dependent Spin Dynamics in Thin Films of TbPc2Nanomagnets Explored by Low-Energy Implanted Muons

We present measurements of the magnetic properties of thin film TbPc2 single-molecule magnets evaporated on a gold substrate and compare them to those in bulk. Zero-fieldmuon spin relaxation measurements were used to determine the molecular spin fluctuation rate of TbPc2 as a function of temperature. At low temperature, we find that the fluctuations in films are much faster than in bulk and depend strongly on the distance between the molecules and the Au substrate. We measure a molecular spin correlation time that varies between 1.4 μs near the substrate and 6.6 μs far away from it. We attribute this behavior to differences in the packing of themagnetic cores, which change gradually on the scale of∼1020 nmaway from the TbPc2/Au interface.