Angular-Resolved Magnetometry Beyond Triclinic Crystals Part II: Torque Magnetometry of Cp*ErCOT Single-Molecule Magnets

The experimental investigation of the molecular magnetic anisotropy in crystals in which the magnetic centers are symmetry related, but do not have a parallel orientation has been approached by using torque magnetometry. A single crystal of the orthorhombic organometallic Cp*ErCOT [Cp*=pentamethylcyclopentadiene anion (C5Me5−); COT=cyclooctatetraenedianion (C8H82−)] single-molecule magnet, characterized by the presence of two nonparallel families of molecules in the crystal, has been investigated above its blocking temperature. The results confirm an Ising-type anisotropy with the easy direction pointing along the pseudosymmetry axis of the complex, as previously suggested by out-of-equilibrium angular-resolved magnetometry. The use of torque magnetometry, not requiring the presence of magnetic hysteresis, proves to be even more powerful for these purposes than standard single-crystal magnetometry. Furthermore, exploiting the sensitivity and versatility of this technique, magnetic anisotropy has been investigated up to 150 K, providing additional information on the crystal-field splitting of the ground J multiplet of the ErIII ion.