Highly functionalised tetrahydroquinolines have been obtained by a modular approach consisting of a nitrone 1,3-dipolar cycloaddition to 2-bromostyrene followed by isoxazolidine N–O cleavage and copper-catalysed aromatic Nsubstitution/cyclisation. A 1,2,3,4-tetrahydro-1,8-naphthyridine was obtained in the same way.
Modular Access to Highly Funtionalised Tetrahydroquinolines / F. M. Cordero; B. B. Khairnar; A. Brandi. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - STAMPA. - 2014:(2014), pp. 7122-7133. [10.1002/ejoc.201403025]
Modular Access to Highly Funtionalised Tetrahydroquinolines.
CORDERO, FRANCA MARIA;KHAIRNAR, BHUSHAN BALASAHEB;BRANDI, ALBERTO
2014
Abstract
Highly functionalised tetrahydroquinolines have been obtained by a modular approach consisting of a nitrone 1,3-dipolar cycloaddition to 2-bromostyrene followed by isoxazolidine N–O cleavage and copper-catalysed aromatic Nsubstitution/cyclisation. A 1,2,3,4-tetrahydro-1,8-naphthyridine was obtained in the same way.
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