The primary aim of this work has been to target new homogeneous catalysts for the selective dehydrogenation of formic acid to hydrogen and carbon dioxide. For this purpose, a variety of different transition metal complexes stabilized by polydentate phosphine ligands has been evaluated and tested.Mechanistic NMR studies and DFT calculations have often complemented the catalytic studies in order to understand the mechanism of substrate activation and pre-catalyst modifications during the catalytic cycle and to highlight differences which could be related to metal and ligand effects.
"Formic Acid Homogeneous catalytic activation by transition metal polydentate phosphine complexes for hydrogen storage and production" / Mellone, Irene. - (2015).
"Formic Acid Homogeneous catalytic activation by transition metal polydentate phosphine complexes for hydrogen storage and production"
MELLONE, IRENE
2015
Abstract
The primary aim of this work has been to target new homogeneous catalysts for the selective dehydrogenation of formic acid to hydrogen and carbon dioxide. For this purpose, a variety of different transition metal complexes stabilized by polydentate phosphine ligands has been evaluated and tested.Mechanistic NMR studies and DFT calculations have often complemented the catalytic studies in order to understand the mechanism of substrate activation and pre-catalyst modifications during the catalytic cycle and to highlight differences which could be related to metal and ligand effects.File | Dimensione | Formato | |
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