Mono- and diatomic I- and I2 building blocks, despite their simplicity, can be used to generate complex hierarchical self-assembled architectures. Herein, the construction of a modular supramolecular poly[3]catenane and its conversion into the axle of an infinite supramolecular pseudo-polyrotaxane were achieved in a seamless process from the starting materials. The unique structural features, directionality, and iodine density of the obtained crystals demonstrate the benefits of a supramolecular design for polyiodide networks intended as solid-state conductors.
Infinite supramolecular pseudo-polyrotaxane with poly[3]catenane axle: Assembling nanosized rings from mono- And diatomic I- and I2 tectons / Savastano M.; Bazzicalupi C.; Gellini C.; Bianchi A.. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 56:(2020), pp. 551-554. [10.1039/c9cc08367g]
Infinite supramolecular pseudo-polyrotaxane with poly[3]catenane axle: Assembling nanosized rings from mono- And diatomic I- and I2 tectons
Savastano M.
Membro del Collaboration Group
;Bazzicalupi C.
Membro del Collaboration Group
;Gellini C.Membro del Collaboration Group
;Bianchi A.Membro del Collaboration Group
2020
Abstract
Mono- and diatomic I- and I2 building blocks, despite their simplicity, can be used to generate complex hierarchical self-assembled architectures. Herein, the construction of a modular supramolecular poly[3]catenane and its conversion into the axle of an infinite supramolecular pseudo-polyrotaxane were achieved in a seamless process from the starting materials. The unique structural features, directionality, and iodine density of the obtained crystals demonstrate the benefits of a supramolecular design for polyiodide networks intended as solid-state conductors.File | Dimensione | Formato | |
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