Chemical guidelines to target a well-defined electronic structure and magnetic anisotropy are of primary importance in physics, chemistry and biology. Our literature overview highlights that engineering the energy gap between the ground and first excited state and tailoring the magnetic anisotropy of paramagnetic molecules is an excellent starting point for boosting the performances of many molecular materials with emerging properties of technological relevance such as Single Molecule Magnets, Pseudo Contact Shift agents, Optically Addressable Qubits, Magnetic Refrigerants, and Magnetic Anisotropy Switches. We also discuss the compatibility between different functionalities
Electronic structure and magnetic anisotropy design of functional metal complexes / Raza, Arsen; Perfetti, Mauro. - In: COORDINATION CHEMISTRY REVIEWS. - ISSN 0010-8545. - ELETTRONICO. - 490:(2023), pp. 215213-215228. [10.1016/j.ccr.2023.215213]
Electronic structure and magnetic anisotropy design of functional metal complexes
Raza, Arsen;Perfetti, Mauro
2023
Abstract
Chemical guidelines to target a well-defined electronic structure and magnetic anisotropy are of primary importance in physics, chemistry and biology. Our literature overview highlights that engineering the energy gap between the ground and first excited state and tailoring the magnetic anisotropy of paramagnetic molecules is an excellent starting point for boosting the performances of many molecular materials with emerging properties of technological relevance such as Single Molecule Magnets, Pseudo Contact Shift agents, Optically Addressable Qubits, Magnetic Refrigerants, and Magnetic Anisotropy Switches. We also discuss the compatibility between different functionalitiesFile | Dimensione | Formato | |
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