The reinvestigation of the solid-state photoreactivity of ethyl (E)-alfa-cyano-2-methoxycinnamate (1) allowed us to obtain the corresponding dimer which was shown to be diethyl (1alfa,2alfa,3beta,4beta)-1,3-dicyano-2,4-bis(2-methoxyphenyl)cyclobutane-1,3-dicarboxylate (2) whose structure was proven on the basis of chemical reactivity and spectroscopic data.
Solid State Photoreactivity of (E)-α-Cyano-2-methoxycinnamate / S. CHIMICHI; P.SARTI-FANTONI; G.COPPINI; F.PERGHEM; G.RENZI. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 52:(1987), pp. 5124-5126. [10.1021/jo00232a013]
Solid State Photoreactivity of (E)-α-Cyano-2-methoxycinnamate
CHIMICHI, STEFANO;SARTI FANTONI, PIERO;RENZI, GIOVANNI
1987
Abstract
The reinvestigation of the solid-state photoreactivity of ethyl (E)-alfa-cyano-2-methoxycinnamate (1) allowed us to obtain the corresponding dimer which was shown to be diethyl (1alfa,2alfa,3beta,4beta)-1,3-dicyano-2,4-bis(2-methoxyphenyl)cyclobutane-1,3-dicarboxylate (2) whose structure was proven on the basis of chemical reactivity and spectroscopic data.File in questo prodotto:
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