High pressure chemical reactions of molecular systems are discussed considering the various factors that can affect the reactivity. These include steric hindrance and geometrical constraints in the confined environment of crystals at high pressure, changes of the free energy landscape with pressure, photoactivation by two-photon absorption, local and collective effects. A classification of the chemical reactions at high pressure is attempted on the basis of the prevailing factors.
From simple to complex and backwards. Chemical reactions under very high pressure / R. Bini; M. Ceppatelli; M. Citroni; V. Schettino. - In: CHEMICAL PHYSICS. - ISSN 0301-0104. - STAMPA. - 398:(2012), pp. 262-268. [10.1016/j.chemphys.2011.04.021]
From simple to complex and backwards. Chemical reactions under very high pressure
BINI, ROBERTO;CEPPATELLI, MATTEO;CITRONI, MARGHERITA;SCHETTINO, VINCENZO
2012
Abstract
High pressure chemical reactions of molecular systems are discussed considering the various factors that can affect the reactivity. These include steric hindrance and geometrical constraints in the confined environment of crystals at high pressure, changes of the free energy landscape with pressure, photoactivation by two-photon absorption, local and collective effects. A classification of the chemical reactions at high pressure is attempted on the basis of the prevailing factors.
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